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The National Park Service mission statement breathes some grand words: The conservation agency intends to preserve the country's natural resources "for the enjoyment, education, and inspiration of this and future generations."

But the Park Service can't keep out air pollution.

A new report published by the National Parks Conservation Association (NPCA) concluded that a whopping 85 percent of parks contend with unhealthy air. The problem is a respiratory toxin regularly created and found in U.S. cities, called ozone. The NPCA found ozone to be a "significant" concern in 87 parks, and a "moderate" issue in 267 parks.

This air pollution wafts into national parks from our potent industrial areas. There's no way to keep it out.

"We’re producing something that's being brought to the pristine areas -- it impacts our remote and thought-to-be-clean places," said Gabriele Pfister, deputy director of the National Center of Atmospheric Research’s atmospheric chemistry lab who had no involvement in the report.

"Ozone is toxic. It damages our airways," she added.

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Ozone comes to life when emissions from vehicles, fossil-fuel power plants, and industry release invisible gases called nitrous oxides, or NOx, into the air. When the sun hits these gases -- along with a mix of other chemicals called volatile organic compounds (VOCs) -- it then creates ozone. "In the morning, the sun comes up, and you start cooking it," explained Pfister. "You start creating ozone."

In some places -- like Pfister's nearby Rocky Mountain National Park -- this air pollution is lifted by normal, rising wind patterns into the mountains.

But pristine, forested land can also make its own ozone. Trees, bushes, and other plants all naturally emit compounds into the air that react with NOx gases and make ozone, explained Anthony Wexler, director of the UC Davis Air Quality Research Center who took no part in the research.

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"You’ll see ozone concentrations in places that aren’t emitting much NOx," said Wexler. "The NOx comes from what we do."

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The solution, at least on paper, is simple. Producing energy and fuel without the combustion processes that make NOx. "Low amounts of NOx would mean low amounts ozone," emphasized Wexler.

In reality, of course, transforming the nation's energy system will require enormous political and societal ambition.

Although there's still ozone swirling around many national parks -- especially those near industrialized areas -- things are certainly much better today than in the 1970s, when air pollution was so bad that Los Angelenos could taste the foul air. This is thanks to the Clean Air Act, which mandated that automakers and industry slash their polluting emissions. "The story is we’ve done a lot to clean up air pollution," said Wexler. "It's a whole lot better than it used to be."

But clearly, air pollution still remains. And in many national parks, you'll breathe it.

Then, of course, there's the growing problem of wildfires -- which create tiny bits of pollution called particulate matter that saturate the skies in many national parks. It's the burnt forest, floating through the air, and there will be more it: A more potent fire regime has emerged out West. Overall, wildfires in the U.S. are burning twice as much land as they were in the early 1980s and they’re burning for weeks, not days, longer.

Ozone formation.Credit: EPA

During the summer of 2018, smoke filled Yosemite Valley. In a large swath of the West, the worst days of particulate pollution are getting worse.

Breathing particulate pollution is bad for your heart, as a number of studies have linked breathing this matter to accelerated heart disease. Meanwhile, ozone damages airways, exacerbates asthma, and -- with prolonged exposure -- can result in premature death, explained Pfister.

That's why Pfister often goes hiking in the morning, before sunlight reacts with NOx to form ozone, which can then find its way into her huffing lungs. "The early bird gets the worm," she said.

But hundreds of millions of national park visitors are inevitably exposed to elevated ozone levels each year. It's a product of our industrialized society, for now.

"When people think of iconic parks like Joshua Tree or the Grand Canyon, they think of unspoiled landscapes and scenic views," said NPCA president Theresa Pierno,in a statement. "I think they would be shocked to know that these are actually some of our most polluted national parks."

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